The characterisation of relative copper isotope amount ratios (δ65Cu) helps constrain a variety of geochemical processes occurring in the geosphere, biosphere and hydrosphere. The accurate and precise determination of δ65Cu in matrix reference materials is crucial in the effort to validate measurement methods. With the goal of expanding the number and variety of available geological and biological materials, we have characterised the δ65Cu values of ten reference materials by MC‐ICP‐MS using C‐SSBIN model for mass bias correction. SGR‐1b (Green River shale), DOLT‐5 (dogfish liver), DORM‐4 (fish protein), TORT‐3 (lobster hepatopancreas), MESS‐4 (marine sediment) and PACS‐3 (marine sediment) have for the first time been characterised for δ65Cu. Additionally, four reference materials (with published δ65Cu values) have been characterised: BHVO‐1 (Hawaiian basalt), BIR‐1 (Icelandic basalt), W‐2a (diabase) and Seronorm? Trace Elements Serum L‐1 (human serum). The reference materials measured in this study possess complex and varied matrices with copper mass fractions ranging from 1.2 µg g?1 to 497 µg g?1 and δ65Cu values ranging from ?0.20‰ to 0.52‰ with a mean expanded uncertainty of ± 0.07‰ (U, k = 2), covering much of the natural copper isotope variability observed in the environment. 相似文献
Pinus taiwanensis is a species endemic to China. This study selected four typical plots of Pinus taiwanensis in the natural secondary forest around Macheng City, in order to reveal the characteristics of and the relationships between different diameter classes (determined based on the diameter at breast height or DBH), forest densities and species diversity, as well as the similarities of species diversity of different plots within the community. The result showed that Pinus taiwanensis was the dominant species in the community. The ratio of Pinus taiwanensis trees of diameter class IV reached a peak of 19.46% of the total followed by diameter class VII at 18.92%. The study recorded 156 species of vascular plants from 130 genera of 71 families; Pinus taiwanensis was the dominant species in the community. When the forest density was 1200 trees ha -1 with the largest average diameter of DBH=36.779±4.444 cm, the diversity (Shannon index H'=1.6716) and the evenness (Pielou index E=0.6727) of the tree layer was the highest. When the forest density reached 1525 trees ha -1 with the lowest average diameter of DBH=18.957±5.141 cm, the richness (Dma=5.4308), the diversity (H'=2.9612) and the evenness (E=0.8985) of all shrub layers climbed to the maximum. When the forest density was 1325 trees ha -1, the richness (Dma=5.8132), the diversity (H'=3.0697) and the evenness (E=0.9025) of all herb layers peaked. In terms of vertical structure, the average diversity indexes were herb layer>shrub layer>tree layer. High canopy density weakened light intensity in the community, causing a reduction in the species diversities of herbs and shrubs. The average similarity coefficient between the sample plots was 0.3356, which was at the medium dissimilarity level. External disturbances and improper management were major contributors to the low species diversity of the community. The implementation of scientific management measures is urgently needed to optimize the forest structures of Pinus taiwanensis, create a benign community environment, and promote species diversities and establish a stable forest community structure. 相似文献
Atlantic salmon reared in recirculating aquaculture system (RAS) may lead to inappropriately high stocking density, because fish live in a limited space. Finding the suitable stocking density of Atlantic salmon reared in RAS is very important for RAS industry. In this paper, the influence of stocking density on growth and some stress related physiological factors were investigated to evaluate the effects of stocking density. The fish were reared for 220 days at five densities (A: 24 kg/m3; B: 21 kg/m3; C: 15 kg/m3; D: 9 kg/ m3 and E: 6 kg/m3 ). The results show that 30 kg/m3 might be the maximum density which RAS can afford in China. The stocking densities under 30 kg/m3 have no effect on mortality of Atlantic salmon reared in RAS. However, the specific growth rate (SGR), final weight and weight gain in the high density group were significantly lower than the lower density groups and middle density groups. Moreover, feed conversion rate (FCR) had a negative correlation with density. Plasma hormone T3 and GH showed significant decrease with the increase of the stocking density of the experiment. Furthermore, thyroid hormone (T3), GH (growth hormone) activities were decreased with stocking density increase. However, plasma cortisol, GOT (glutamic oxalacetic transaminase) and GPT (glutamic pyruvic transaminase) activities were increase with stocking density increase. And the stocking density has no effects on plasma lysozyme of Atlantic salmon reared in RAS. These investigations would also help devise efficient ways to rear adult Atlantic salmon in China and may, in a way, help spread salmon mariculture in China.